イベント・セミナー・講演会

Controlling the optical properties of carbon nanotubes by chemical modification: computational studies

  • RSS

日程
2017年7月31日(月)
時間
15:00 -
場所
大岡山キャンパス別窓 本館2階 H284B 物理学系輪講室
講師
Professor JUHASZ Gergely (Department of Chemistry, School of Science, Tokyo Institute of Technology)
備考
連絡教員:物理学系 斎藤晋(内線2070)

量子物理学・ナノサイエンス第192回セミナー

概要

Single-walled carbon nanotubes (SWNTs) have characteristic luminescence peaks in nearinfrared region. One of the main practical challenges of utilizing this luminescence is the low intensity of the peaks due to low-energy "dark" excitons. However, a radical increase of intensity as well as a red shift can be observed for nanotubes after chemical modification in their wall. We study the effect of such modifications, ozone doping and sp3 doping of SWNTs, using Density-Functional Tight-Binding (DFTB) method. Dopants like ozone and several sp3 dopants break the symmetry of the nanotube locally, allowing radiative transitions from the previously "dark" excitons. Some chemical modifications also create excess spindensity on the carbon nanotube wall, leading to preferential patterns of doping and controllable luminescence peaks. We also briefly discuss possible chemical strategies to control the optical properties by proximal doping. DFTB offers a significant speedup compared to DFT, which makes it especially suitable to study such local distortions and electronic states of systems at nano-scale.

  • ナノサイエンス・量子物理学国際研究センター 主催
  • 東京工業大学理学院・物理学系、「ナノサイエンスを拓く量子物理学拠点」共催

更新日:2017.07.28

  • RSS

ページのトップへ

CLOSE

※ 東工大の教育に関連するWebサイトの構成です。

CLOSE