Breakthrough in blending metals: Precise control of multimetallic one-nanometer cluster formation achieved

Background

Multimetallic clusters — typically composed of three or more metals — are garnering attention as they exhibit properties that cannot be attained by single-metal materials. If a variety of metal elements are freely blended, it is expected that as-yet-unknown substances are discovered and highly-functional materials are developed. So far, no one had reported the multimetallic clusters blended with more than four metal elements so far because of unfavorable separation of different metals. One idea to overcome this difficulty is miniaturization of cluster sizes to one-nanometer scale, which forces the different metals to be blended in a small space. However, there was no way to realize this idea.

Overview

A team, including Takamasa Tsukamoto, Takane Imaoka, Kimihisa Yamamoto and colleagues, has developed an atom hybridization method, which has realized the first-ever synthesis of multimetallic clusters consisting of more than five metal elements with precise control of size and composition. This method employs a dendrimer template² that serves as a tiny “scaffold” to enable controlled accumulation of metal salts. After precise uptake of the different metals into the dendrimer, multimetallic clusters are obtained by chemical reduction. (See Figure 1.) In contrast, a conventional method without the dendrimer yields enlargement of cluster sizes and separation of different metals. (See Figure 2.)

A conventional method without the dendrimer template

Figure 2. A conventional method without the dendrimer template

Large clusters (of over 10-nanometers) are obtained, and different metals are separated from each other.

The team successfully demonstrated the formation of five-element clusters composed of gallium (Ga), indium (In), gold (Au), bismuth (Bi) and tin (Sn), as well as iron (Fe), palladium (Pd), rhodium (Rh), antimony (Sb) and copper (Cu), and a six-element cluster consisting of Ga, In, Au, Bi, Sn and platinum (Pt). Additionally, they hint at the possibility of making clusters composed of eight metals or more.

Future Development

This atom hybridization method using the dendrimer template can synthesize ultrasmall multimetallic clusters with precise control of size and composition. There are more than 90 metals in the periodic table. With infinite combinations of metal elements, atomicity and composition, this method will open up a new field in chemistry on a one-nanometer scale. The current study marks a major step forward in creating such as-yet-unknown innovative materials.

Technical terms

¹ Atom hybridization

A method for synthesis of multimetallic clusters on a one-nanometer scale by using a dendrimer² as a nanosized template. Various metal ions can be taken up into the dendrimer structure with various combinations. Multimetallic clusters are obtained by chemical reduction of these metal ions on the template.

² Dendrimer template

A dendrimer is a specific macromolecule having repetitively branched structures. The team utilizes a dendrimer template suitably designed for the assembly of metal atoms in controlling the number of atoms.

Reference

Authors :	Takamasa Tsukamoto¹, Tetsuya Kambe^{1, 2}, Aiko Nakao³, Takane Imaoka^{1, 2, 4}, Kimihisa Yamamoto^{1, 2,*}
Title of original paper :	Atom-hybridization for synthesis of polymetallic clusters
Journal :	Nature Communications
DOI :	10.1038/s41467-018-06422-8
Affiliations :	¹ JST-ERATO, Yamamoto Atom Hybrid Project, Institute of Innovative Research, Tokyo Institute of Technology ² Laboratory for Chemistry and Life Science, Tokyo Institute of Technology ³ RIKEN ⁴ JST-PRESTO