Shedding Light on the Development of Efficient Blue-Emitting Semiconductors

September 24, 2020

Scientists at Tokyo Institute of Technology (Tokyo Tech) have discovered a new alkali copper halide, Cs₅Cu₃Cl₆I₂, that emits pure blue light. The combination of the two halide ions, chloride and iodide, gives the material a crystalline structure made of zigzag chains and peculiar properties that result in highly efficient photoluminescence. This novel compound could be readily used to produce relatively inexpensive and eco-friendly white LEDs and reduce the energy used in the generation of everyday artificial light.

A Highly Efficient and Stable Blue-Emitting Cs5Cu3Cl6I2 with a 1D Chain Structure

Artificial light accounts for approximately 20% of the total electricity consumed globally. Considering the present environmental crisis, this makes the discovery of energy-efficient light-emitting materials particularly important, especially those that produce white light. Over the last decade, technological advances in solid-state lighting, the subfield of semiconductors research concerned with light-emitting compounds, has led to the widespread use of white LEDs. However, most of these LEDs are actually a blue LED chip coated with a yellow luminescent material; the emitted yellow light combined with the remaining blue light produces the white color.

Therefore, a way to reduce the energy consumption of modern white LED lights is to find better blue-emitting semiconductors. Unfortunately, no known blue-emitting compounds were simultaneously highly efficient, easily processible, durable, eco-friendly, and made from abundant materials—until now.

In a recent study, published in Advanced Materials, a team of scientists from Tokyo Institute of Technology, Japan, discovered a new alkali copper halide, Cs₅Cu₃Cl₆I₂, that fills all the criteria. Unlike Cs₃Cu₂I₅, another promising blue-emitting candidate for future devices, the proposed compound has two different halides, chloride and iodide. Although mixed-halide materials have been tried before, Cs₅Cu₃Cl₆I₂ has unique properties that emerge specifically from the use of I⁻ and Cl⁻ ions.

It turns out that Cs₅Cu₃Cl₆I₂ forms a one-dimensional zigzag chain out of two different subunits, and the links in the chain are exclusively bridged by I⁻ ions. The scientists also found another important feature: its valence band, which describes the energy levels of electrons in different positions of the material's crystalline structure, is almost flat (of constant energy). In turn, this characteristic makes photo-generated holes—positively charged pseudoparticles that represent the absence of a photoexcited electron—"heavier." These holes tend to become immobilized due to their strong interaction with I⁻ ions, and they easily bond with nearby free electrons to form a small system known as an exciton.

Excitons induce distortions in the crystal structure. Much like the fact that one would have trouble moving atop a suspended large net that is considerably deformed by one's own weight, the excitons become trapped in place by their own effect. This is crucial for the highly efficient generation of blue light. Professor Junghwan Kim, who led the study, explains: "The self-trapped excitons are localized forms of optically excited energy; the eventual recombination of their constituting electron–hole pair causes photoluminescence, the emission of blue light in this case."

In addition to its efficiency, Cs₅Cu₃Cl₆I₂ has other attractive properties. It is exclusively composed of abundant materials, making it relatively inexpensive. Moreover, it is much more stable in air than Cs₃Cu₂I₅ and other alkali copper halide compounds. The scientists found that the performance of Cs₅Cu₃Cl₆I₂ did not degrade when stored in air for three months, while similar light-emitting compounds performed worse after merely days. Finally, Cs₅Cu₃Cl₆I₂ does not require lead, a highly toxic element, making it eco-friendly overall.

Excited about the results of the study, Prof. Kim concludes: "Our findings provide a new perspective for the development of new alkali copper halide candidates and demonstrate that Cs₅Cu₃Cl₆I₂ could be a promising blue-emitting material." The light shed by this team of scientists will hopefully lead to more efficient and eco-friendly lighting technology.

Reference

Authors :	Jiangwei Li¹, Takeshi Inoshita^1,2, Tianping Ying¹, Atsushi Ooishi³, Junghwan Kim¹,and Hideo Hosono^1,2
Title of original paper :	A Highly Efficient and Stable Blue-Emitting Cs₅Cu₃Cl₆I₂ with a 1D Chain Structure
Journal :	Advanced Materials
DOI :	10.1002/adma.202002945
Affiliations :	¹ Materials Research Center for Element Strategy, Tokyo Institute of Technology ² National Institute for Materials Science ³ Science and Innovation Center, Mitsubishi Chemical Corporation