Could the heat of the Earth’s crust become the ultimate energy source?

Scientists at Tokyo Institute of Technology and Sanoh Industrial developed a very stable battery cell that can directly convert heat into electricity, thus finally providing a way for exploiting geothermal energy in a sustainable way.

Here, the height of the building represents the energy state of electrons. Electrons in the semiconductor layer rise to a high-energy state by becoming thermally excited and then transfer to the electron transport layer. Then, they go through an external circuit and reach the counter electrode. Redox reactions take place in the electrolyte layer next to the counter electrode, providing the semiconductor with low-energy electrons. In spite of providing continuous heating, this process eventually stops as the different copper ions in the electrolyte relocate. However, the battery can revert this situation by opening the external circuit for a certain duration.

In a world where energy consumption is on the rise, our only hope is the development of new energy-generation technologies. Although currently used renewable energy sources such as wind and solar energy have their merits, there is a gigantic, permanent, and untapped energy source quite literally under our noses: geothermal energy.

Generating electricity from geothermal energy requires devices that can somehow make use of the heat within the Earth's crust. Recently, a team of scientists at Tokyo Tech, led by Dr. Sachiko Matsushita, have made great progress in the understanding and development of sensitized thermal cells (STCs), a kind of battery that can generate electric power at 100 ℃ or less.

Several methods for converting heat into electric power exist, however, their large-scale application is not feasible. For example, hot-and-cold redox batteries and devices based on the Seebeck effect are not possible to simply bury them inside a heat source and exploit them.

Dr. Matsushita's team have previously reported the use of STCs as a new method for converting heat directly into electric power using dye-sensitized solar cells. They also replaced the dye with a semiconductor to allow the system to operate using heat instead of light. Figure 1 illustratively represents the STC, a battery that consists of three layers sandwiched between electrodes: an electron transport layer (ETM), a semiconductor layer (germanium), and a solid electrolyte layer (copper ions). In short, electrons go from a low-energy state to a high-energy state in the semiconductor by becoming thermally excited and then get transferred naturally to the ETM. Afterwards, they leave through the electrode, go through an external circuit, pass through the counter electrode, and then reach the electrolyte. Oxidation and reduction reactions involving copper ions take place at both interfaces of the electrolyte, resulting in low-energy electrons being transferred to the semiconductor layer so that the process can begin anew, thus completing an electric circuit.

However, it was not clear at that time whether such a battery could be used as a perpetual engine or if the current would stop at some point. After testing, the team observed that electricity indeed stopped flowing after a certain time and proposed a mechanism explaining this phenomenon. Basically, current stops because the redox reactions at the electrolyte layer stop owing to the relocation of the different types of copper ions. Most importantly, and also surprisingly, they found out that the battery can revert this situation itself in the presence of heat by simply opening the external circuit for some time; in other words, by using a simple switch. "With such a design, heat, usually regarded as low-quality energy, would become a great renewable energy source," states Matsushita.

The team is very excited about their discovery because of its applicability, eco-friendliness, and potential for helping solve the global energy crisis. "There is no fear of radiation, no fear of expensive oil, no instability of power generation like when relying on the sun or the wind," remarks Matsushita. Further refinements to this type of battery will be the aim of future research, with the hope of one day solving humanity's energy needs without harming our planet.

Reference

Authors :	S. Matsushita1*, T. Araki1, B. Mei2, S. Sugawara1, Y. Inagawa1, J. Nishiyama2, T. Isobe1, and A. Nakajima1
Title of original paper :	A sensitized thermal cell recovered using heat
Journal :	Journal of Materials Chemistry A
DOI :	10.1039/C9TA04060A
Affiliations :	1Department of Materials Science and Engineering, Tokyo Institute of Technology 2Research & Development Center, Sanoh Industrial Co., Ltd

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